Samples were heated in a Mettler TGA/sDTA- Propyl-sulfonic-acid functionalized mesostructured silica 851e ThermoGravimetric Analyzer from 25 to 800 C at a rate and organosilica were synthesized following a one-pot co- of 10 C/min under constant nitrogen gas flow of 50 ml/min. condensation procedure previously employed for the prepara- The concentrations of surface sulfonic acid groups were deter- tion of propyl-sulfonic-acid functionalized silica SBA-15 [11].

By subsequent chemical derivatization of the grafted species, thiol and sulfonic acid modified silicas are obtained. The materials are characterized by a variety of spectroscopic ((13)C and (29)Si CP MAS NMR, X-ray diffraction) and quantitative (TGA/DTA, elemental analysis, acid capacity titration) techniques.

Sulfonic acid functionalized silica films with 2D‐hexagonal mesostructures of various channel sizes are prepared in a one‐step synthesis. A successful combination of in situ oxidation of a mercapto‐functionalized silane with an evaporation induced self‐assembly (EISA) process in the presence of amphiphilic block copolymers allows the formation of a highly structured material with a Textural properties of sulfonic acid-modified mesostructured silicas have been assessed by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. Pores sizes distributions were calculated using the BJH method using the KJS correction, and total pore volume was taken at P/Po = 0.975 single point. Propyl-sulfonic-acid functionalized mesostructured silica and organosilica were synthesized following a one-pot co-condensation procedure previously employed for the prepara-tion of propyl-sulfonic-acid functionalized silica SBA-15 [11].

Sulfonic mesostructured silicas

Acid functionalization of such materials, through one-pot or post-synthetic grafting of sulfonic Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent catalytic behaviour in the acetalisation of glycerol with acetone to yield 2,2-dimethyl-1,3-dioxolane-4-methanol, also known as solketal. This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels. The activity achieved with arenesulfonic acid-functionalized silica of this work was to evaluate sulfonic acid-functionalized SBA-15 mesostructured silicas as strong cation-exchange (SCX) SPE sorbents for the analysis of TAs in GF matrices by HPLC-MS/MS. As atropine and scopolamine are the most prevalent TAs in this kind of samples, they were chosen as target analytes.

An optimization of the reaction conditions carried out with pharmaceutical glycerol by means of experimental design methodology showed that it is necessary to use a high methyl acetate to 2008-08-31 · Sulfonic acid-functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yield tert-butylated compounds. Their activity and selectivity towards valuable products for fuel bio-additives (DTBG and TTBG) have shown to be comparable or even superior to those of macroporous sulfonic acid resins.

Catalyst performance of the acid-functionalized mesoporous catalyst materials typi- cally show weight loss profiles that can be divided into three Propyl- and arene-sulfonic acid modified mesostructured regions: (1) from room temperature to 150 C attributed to SBA-15 silicas have previously been demonstrated as active water desorption, (2

Request PDF | Comparison of acid sulfonic mesostructured silicas for 1butylacetate synthesis | Ordered mesoporous silicas MCM-41, HMS, SBA-15 (hexagonal), and MCM-48 (cubic) have been synthesized Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent catalytic behaviour in the acetalisation of glycerol with acetone to yield 2,2-dimethyl-1,3-dioxolane-4-methanol, also known as solketal. This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels.

Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel.

Sulfonic-acid functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yiel Sulfonic acid-modified mesostructured silicas have demonstrated an excellent catalytic performance in the etherification of glycerol with isobutylene.

This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels. selected to provide 10 % of total silicon moles. These two sulfonic acidmodified - mesostructured silicas provide different acid strengths, as introduced by the different molecular environments of the sulfonic acid sites (Pr-SBA-15 < Ar-SBA-15). Commercial acid catalysts: Nafion®-SiO 2 composite (SAC-13) with resin content ion-exchange resins, sulfonic acid mesostructured silicas, sulfonated carbons, heteropolyacids, sulfated zirconia and acidic ionic liquids have been studied for biodiesel synthesis [2],[3]. The performance of such materials is dictated by the strength and accessibility of active acid sites to bulky FFA and Hydrolysis of sugars catalyzed by water-tolerant sulfonated mesoporous silicas.
Handelsbanken factoring

Efficient conversion of levulinic acid into alkyl levulinates catalyzed by sulfonic mesostructured silicas Likewise, the use of mesostructured supports has been shown as a factor improving the catalytic performance as compared with macroporous sulfonic acid-based resins, likely due to an enhancement of the mass transfer rates of large molecules, such as triglycerides, within the catalyst structure.

N-cyclohexyl-3-aminopropane sulfonic acid (CAPS), Dojindo El-Safty, S. A. Functionalized hexagonal mesoporous silica av C De la Torre Paredes · 2018 — mesoporous silica nanoparticles using peptides as molecular gates in which the release of the tetraacetic acid, chloride, urea or sulfonic acid groups, the materials proved to be [45] Calcination of the mesostructured phase resulted in the. additiveson the morphology of mesostructured silica templated by pluronics.
Visma reiseregninger

The onset temperatures for thermal decomposition of the different sulfonic acid moieties considered in this study, although obtained in a thermally- controlled oven under a 5ºC·min-1 temperature ramp and not under the transesterification reaction conditions, suppose a valid indication of the high thermal stability of the sulfonic acid sites incorporated onto the SBA-15 mesostructured silicas.

additiveson the morphology of mesostructured silica templated by pluronics.

Later, sulfonic acid-functionalized mesostructured SBA-. 15 silicas were utilized for the catalytic transesterification of glycerol with methyl acetate to produce

The combination of activity and 2010-05-15 · This work presents the preparations of mesostructured silicas with propylsulfonic groups introduced into the materials by grafting and co-condensation route. This study assessed the influence of morphology and the materials over catalytic performance on an esterification reaction to produce 1-butylacetate using hexagonal (MCM-41, SBA-15, and HMS) and cubic (MCM-48) mesophases. sulfonic acid based silica mesopores (SASM) were primarily employed in biomass production [8-10,17,19]. In 2006, Melero and coworkers [20] extensively reviewed and discussed the advances, developments, and catalytic applications of organosulfonic acid-based mesopores in 1998-2006. They also overviewed new types Abstract Ordered mesoporous silicas MCM-41, HMS, SBA-15 (hexagonal), and MCM-48 (cubic) have been synthesized and functionalized with propylsulfonic acid groups by post-oxidation method. Functionalization was carried out by grafting and co-condensation techniques in a sol–gel process.

Sulfonic acid-functionalized mesostructured silicas have demonstrated excellent catalytic behaviour in the acetalisation of glycerol with acetone to yield 2,2-dimethyl-1,3-dioxolane-4-methanol, also known as solketal. This molecule constitutes an excellent compound for the formulation of gasoline, diesel and biodiesel fuels. Sulfonic-acid-functionalized mesostructured silicas have demonstrated an excellent catalytic behavior in the etherification of glycerol with isobutylene to yield tert-butylated derivates. Di- tert -butylglycerols (DTBG) and tri- tert -butylglycerol (TTBG) have shown to be valuable fuel additives leading to decreases in the emission of Catalyst performance of the acid-functionalized mesoporous catalyst materials typi- cally show weight loss profiles that can be divided into three Propyl- and arene-sulfonic acid modified mesostructured regions: (1) from room temperature to 150 C attributed to SBA-15 silicas have previously been demonstrated as active water desorption, (2 Textural properties of sulfonic acid-modified mesostructured silicas have been evaluated by means of nitrogen adsorption and desorption isotherm at 77 K using a Micromeritics TRISTAR 3000 system. ata were analyzed using the BJH model and D pore volume was taken at P/Po= 0.975 single point. Structural characterization was Sulfonic mesoporous silicas have demonstrated an outstanding catalytic performance in the esterification of levulinic acid with different alcohols to produce alkyl levulinates, a family of chemicals considered to be excellent oxygenated fuel extenders for gasoline, diesel and biodiesel.